振荡是将可用激光波长转换成蓝绿色和近红外光谱区域的重要过程。

参数

物理和化学特性

化学式KNbO3
晶体结构斜方,mm2
晶格参数a = 5.6896Å, b = 3.9692Å, c = 5.7256Å
质量密度4.617 g/cm3
熔点1333 K
居里温度498 K
介电轴和结晶轴的分配 X, Y, Z ⇒ b, a, c
P = 0.101325MPa时的比热cpcp = 767 J/kgK
导热系数κ > 3.5 W/mK
热膨胀aa=5.010×10-6/℃; ab=1.410×10-5/℃; ac=5.010×10-7/℃

线性光学性质
属性数值
透明范围400-5500 nm
红外截止波长5.5 μm
吸收损失<=1%/cm 在1064 nm
损坏阈值<= 4 J / cm2在527 nm(500ps,单脉冲)
<= 6 J / cm2在1054 nm(700ps,单脉冲)

非线性光学性质
属性数值
非线性光学系数d31=-15.8 pm/V, d32=-18.3 pm/V at 1064 nm
最短SHG波长425 nm(Ⅰ型NCPM,y切或a切)
Ⅰ型SHG的接受角为1064 nmDq = 0.24 mrad / cm(内部)
Ⅰ型SHG的接受温度为1064 nmDT=0.3 ℃/cm

线性吸收系数
λ [μm]α [cm−1]Note
0.4230.13 ± 0.02沿轴,E || c
0.458–0.5150.04–0.07
0.8–1.10.001–0.003
0.820.015
0.8460.000034 ± 0.000022沿轴,E || b
1.06420.0018–0.0025沿b轴
30.05沿c轴
0.03沿a轴
3.50.05沿c轴
0.02沿a轴
40.08沿c轴
0.08沿a轴
4.50.27沿c轴
0.45沿a轴
51.21沿c轴
1.85沿a轴
5.57.6沿c轴
4.9沿a轴

双光子吸收系数
λ [μm]τp [ns]β × 1011 [cm/W]
0.846CW320 ± 50

T = 295K时的折射率实验值
λ [μm]nXnYnZ
0.432.49742.41452.2771
0.4882.41872.35272.2274
0.5142.39512.33372.2121
0.6332.32962.28012.1687
0.862.27842.23722.1338
1.0642.25762.21952.1194
1.52.23412.19922.1029
22.21592.18322.0899
2.52.19812.16742.0771
32.17852.14982.063

非线性折射率γ
λ [μm]γ × 1015 [cm2/W]Note
0.851.87 ± 0.35沿Y
有效二阶非线性系数
XY平面deeo = d32 sin2 φ + d31 cos2 φ
YZ平面dooe = d32 sin θ
XZ平面,θ<Vzdoeo = deoo = d31 sin θ
XZ平面,θ> Vzdooe = d31 sin θ

二阶非线性系数的绝对值
|d32(0.852 μm)| = 11.0 ± 0.6 pm/V
|d33(0.852 μm)| = 22.3 ± 1.1 pm/V
|d24(1.064 μm)| = 12.5 ± 0.6 pm/V
|d32(1.064 μm)| = 10.8 ± 0.6 pm/V
|d33(1.064 μm)| = 19.6 ± 1.0 pm/V
|d32(1.313 μm)| = 9.2 ± 0.5 pm/V
|d33(1.313 μm)| = 16.1 ± 0.8 pm/V

二阶非线性系数的相对值
|d15(1.064 μm)| = (41.2 ± 0.8) × d11(SiO2) = 12.4 ± 0.2 pm/V
|d24(1.064 μm)| = (42.8 ± 0.8) × d11(SiO2) = 12.8 ± 0.2 pm/V
|d31(1.064 μm)| = (39.5 ± 0.6) × d11(SiO2) = 11.9 ± 0.2 pm/V
|d32(1.064 μm)| = (45.7 ± 0.6) × d11(SiO2) = 13.7 ± 0.2 pm/V
|d33(1.064 μm)| = (68.5 ± 0.6) × d11(SiO2) = 20.6 ± 0.2 pm/V

相位匹配角的实验值(T = 293 K)
相互作用波长[μm]φexp [deg]θexp [deg]
XY平面,θ=90◦
SHG, e + e ⇒ o
0.946 ⇒ 0.473≈30
4.7599 ⇒ 2.3799569.9
YZ 平面, φ = 90◦
SHG, o + o ⇒ e
0.86 ⇒ 0.43
83.5
0.89 ⇒ 0.445
70.7
0.92 ⇒ 0.46
64
0.94 ⇒ 0.47
60.5
1.0642 ⇒ 0.5321
46.4
1.3188 ⇒ 0.6594
30.6
1.3382 ⇒ 0.6691
29.7
3.5303 ⇒ 1.76515
37.3
4.7291 ⇒ 2.36455
77.3
SFG, o + o ⇒ e
1.3188 + 0.6594 ⇒ 0.4396
62.3
1.3188 + 1.0642 ⇒ 0.5889
37.7
4.7762 + 3.1841 ⇒ 1.9105
46.6
5.2955 + 3.5303 ⇒ 2.1182
59.5
XZ 平面, φ = 0◦, θ > Vz
SHG, o + o ⇒ e
1.0642 ⇒ 0.5321
70.4
1.3188 ⇒ 0.6594
56.8
1.3382 ⇒ 0.6691
56.2
3.5303 ⇒ 1.76515
58.8
SFG, o + o ⇒ e
1.3188 + 1.0642 ⇒ 0.5889
62.6
5.2955 + 3.5303 ⇒ 2.1182
86.1

NCPM温度的实验值
相互作用波长[μm]T [◦C]
沿X轴
SHG, type I
0.972 ⇒ 0.486−20
0.982 ⇒ 0.49118.7
0.986 ⇒ 0.49320
0.988 ⇒ 0.49420
1.047 ⇒ 0.5235162
1.0642 ⇒ 0.5321178
沿Y轴
SHG, type I
0.8385 ⇒ 0.41925−34.2
0.8406 ⇒ 0.4203−28.3
0.842 ⇒ 0.421−22.8
0.846 ⇒ 0.423-11.5
0.856 ⇒ 0.42815
0.857 ⇒ 0.428520
0.8593 ⇒ 0.4296520
0.86 ⇒ 0.4322
0.8615 ⇒ 0.4307530
0.862 ⇒ 0.43134
0.879 ⇒ 0.439570
0.9289 ⇒ 0.46445158
0.95 ⇒ 0.475180
SFG, type I
0.6764 + 1.0642 ⇒ 0.41355-4
0.6943 + 1.0642 ⇒ 0.4201727.2

内部角带宽的实验值
相互作用波长[μm]T [◦C]θpm [deg]Δθint [deg]Δφint [deg]
XZ平面,φ=0◦
SHG, o + o ⇒ e
1.0642 ⇒ 0.532120710.013–0.014
沿Y轴
SHG, type I
0.857 ⇒ 0.428520900.6591.117

温度带宽的实验值
相互作用波长[μm]T [◦C]θpm [deg]ΔT [◦C]
沿X轴
SHG, type I
0.982 ⇒ 0.49118.7900.95
1.0642 ⇒ 0.5321181900.27–0.32
沿Y轴
SHG, type I
0.8385 ⇒ 0.41925−34.2900.27
0.842 ⇒ 0.421−22.8900.3
0.855 ⇒ 0.427526.4900.265
0.92 ⇒ 0.46163.5900.285
SFG, type I
0.6764 + 1.0642 ⇒ 0.41355-4900.35

T = 295 K时温度带宽的实验值
相互作用波长[μm]θexp [deg]ΔT [◦C]
YZ 平面, φ = 90◦
SHG, o + o ⇒ e
1.0642 ⇒ 0.532146.40.39
1.3382 ⇒ 0.669129.70.59
3.5303 ⇒ 1.7651537.12.3
SFG, o + o ⇒ e
5.2955 + 3.5303 ⇒ 2.118259.52.4
XZ 平面, φ = 0◦, θ >Vz
SHG, o + o ⇒ e
1.0642 ⇒ 0.532171.40.77
1.3382 ⇒ 0.669156.22.2
3.5303 ⇒ 1.7651558.110.1

非临界SHG的温度调节(λ1以μm为单位,T以℃为单位)。
沿X轴λ1 = 0.97604 + 2.53 × 10−4 T + 1.146 × 10−6 T 2
沿Y轴λ1 = 0.85040 + 2.94 × 10−4 T + 1.234 × 10−6 T 2

非临界SHG工艺的双折射温度变化
沿X轴(1.0642 μm ⇒ 0.5321 μm)1.10 × 10−4 K−1
沿Y轴(0.92 μm ⇒ 0.46 μm)1.43 × 10−4 K−1

激光诱导的表面损伤阈值
λ [μm]τp [ns]Ithr [GW/cm2]Note
0.5270.58.8–9.4沿b轴,E || c

12–15沿b轴,E⊥c
0.5321250.15–0.18
100.055
0.80.0002>2001 kHz
1.04711>0.034 kHz, 2000小时
1.0540.711沿a轴,E⊥c

18沿b轴,E⊥c

37沿b轴,E || c
1.0642250.15–0.18

0.1>100

光谱

KNbO3-相位匹配角的温度变化

室温下KNbO3的折射率分散

KNbO3-透射光谱

KNbO3-光学吸收

 

特点应用